Waec Chemistry 1990 Past Questions and Answers

Question 41:

• WAEC 1990

(a) Arrange the first three members of the halogen family in their increasing order of electronegativity. Give the reason for your answer.
(b) State and explain what happens when chlorine reacts with starch iodide paper.

Question 42:

• WAEC 1990

(a) Name the type of solid structure possessed by:
(i) diamond;
(ii) iodine;
(iii) sodium chloride.

(b) Give:
(i) one alloy of tin:
(ii) a common reducing agent which is a compound of tin.

Question 43:

• WAEC 1990

Liquefied air is mainly a mixture of nitrogen and oxygen which can be separated into its components by fractional distillation (Boiling point of nitrogen is 196°C, Boiling point of oxygen is 174°C)
(a) Name the fraction which distills over first. Give the reason for your answer.
(b) Give another industrial application of fractional distillation as a separation technique.

Question 44:

• WAEC 1990

(a)(i) List two physical properties used as criteria for purity of substances
(ii) describe how you would prepare a pure, dry sample of sodium chloride crystals by a neutralization reaction, using bench reagents.
(iii) Give two other general methods for preparing soluble salts.

(b) Explain the following observations:
(i) a sheet of iron placed in dilute copper (II) tetraoxosulphate (VI) solution reddish brown;
(ii) the white gelatinous precipitate formed when a few drops of sodium hydroxide solution are added to a solution of aluminium salt dissolves in excess alkali;
(iii) the pale green prepared iron(II) chloride solution changes to brown on bubbling chlorine gas through it.
(iv) Write a balanced equation for the reaction of dilute hydrochloric acid with marble. List two industrial process in which limestone is used as a raw material.

Question 45:

• WAEC 1990

Consider the reaction represented by the equation: 2SO\(_{2(g)}\) + O\(_{2(g)}\) 2SO\(_{3(g)}\). \(\Delta\)H = 188KJ.
(a) Write an expression for the equilibrium constant
(b) Sketch an energy diagram for the forward reaction, showing the profile for the catalyzed and non-catalyzed systems.
(c) state the reason, the effect of the following on the position of equilibrium of the system:
(i) increase in temperature
(ii) increase in pressure;
(iii) removal of some of the SO\(_3\) produced;
(iv) presence of V\(_2\)O\(_5\)
(d)(i) Write equations to show how the sulphur(VI) oxide is converted to tetraoxosulphate(VI) acid in the contact process
(ii) Give two uses of tetraoxosulphate(VI) acid.