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(a)(i) Draw and label a diagram for the laboratory preparation of a dry sample of ...

(a)(i) Draw and label a diagram for the laboratory preparation of a dry sample of sulphur(IV)oxide.
(ii) Write a balanced chemical equation for the reaction in (a)(i).
(iii) State the precaution that must be taken in the preparation of the gas stated in (a)(i).
(iv) Give a reason why the precaution stated in (a)(ii) must be taken.

(b)(i) State Dalton's law of partial pressures.
(ii) The volume of a sample of methane collected over-water at a temperature of 12°C and a pressure of 700 mmHg was 30cm\(^3\). Calculate the volume of the dry gas at s.t.p. [Saturated vapour pressure of water at 12°C is 10 mmHg] •

(c)(i) Write an equation for the reaction between chlorine and water.
(ii) Why does litmus paper turn red when put in the resulting solution in (c)(i)?

(d)(i) State the trend in the boiling points of chlorine, bromine and iodine.
(ii) Explain briefly why water has a higher boiling point than ammonia.



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